Au(111) - \(\ce{ BMP-TFSI }\)
echemdb identifier: atkin_2009_afm_13266_f4a_solid
tags:
A cyclic voltammogramm for Au(111) recorded in \(\ce{ BMP-TFSI }\) at a scan rate of \(10 \; \mathrm{mV\,s^{-1}}\) from Figure 4a in R. Atkin et al. Zein El Abedin. S., Hayes, R., Gasparotto, LHS, Borisenko, N., Endres, F.,“AFM and STM studies on the surface interaction of [BMP] TFSA and [EMIm] TFSA ionic liquids with Au \(III\)”, J. Phys. Chem. C, 113:13266–13272, 2009.
Further information
The figure shows digitized data.
The Au(111) electrode was prepared by:
* Annealed at 350°C for 4h under vacuum in a quartz ampule.
Comment left by the curator on the published figure A baseline for zero current was not available and hence was chosen by the curator. The actual data has more noise than the digitized data.
Metadata
Details on the electrochemical system (yaml)
electrodes:
- crystallographicOrientation: poly
function: counter electrode
material: Pt
name: CE
shape:
type: wire
- function: reference electrode
material: Pt
name: REF
shape:
type: wire
- crystallographicOrientation: '111'
description: Au on mica
function: working electrode
geometricElectrolyteContactArea:
unit: cm-2
value: 0.3
material: Au
name: WE
preparationProcedure:
description:
- "Annealed at 350\xB0C for 4h under vacuum in a quartz ampule."
source:
manufacturer: Molecular Imaging
electrolyte:
components:
- name: BMP-TFSI
proportion:
unit: volume percent
value: 100
purity:
refinement: "vacuum dried at 120 \xB0C"
source:
purity:
grade: ultrapure
supplier: MERCK/emd
type: solvent
temperature:
unit: K
value: 298.15
type: ionic liquid
type: electrochemical
Citation key (bibtex)
@article{atkin_2009_afm_13266,
author = "Atkin, R and Borisenko, N and Drüschler, M",
title = "Zein El Abedin",
journal = "S., Hayes, R., Gasparotto, LHS, Borisenko, N., Endres, F.,“AFM and STM studies on the surface interaction of [BMP] TFSA and [EMIm] TFSA ionic liquids with Au (III)”, J. Phys. Chem. C",
volume = "113",
pages = "13266--13272",
year = "2009"
}
Details about the original figure in the publicaton (yaml).
comment: A baseline for zero current was not available and hence was chosen by the
curator. The actual data has more noise than the digitized data.
fields:
- name: E
orientation: horizontal
reference: Fc/Fc+
type: number
unit: V
- name: j
orientation: vertical
type: number
unit: mA / cm2
measurementType: CV
scanRate:
unit: mV / s
value: 10.0
simultaneousMeasurements: []
type: digitized
Details about the curation process of this entry (yaml).
process:
- date: '2022-01-10'
name: Jerome Mayer
orcid: https://orcid.org/0000-0002-7451-9994
role: curator
- date: '2024-02-29'
name: Albert Engstfeld
orcid: https://orcid.org/0000-0002-9686-3948
role: reviewer