Au(111) - \(\ce{ BMP-TFSI }\)

echemdb identifier: atkin_2009_afm_13266_f4a_solid
tags:

A cyclic voltammogramm for Au(111) recorded in \(\ce{ BMP-TFSI }\) at a scan rate of \(10 \; \mathrm{mV\,s^{-1}}\) from Figure 4a in R. Atkin et al. Zein El Abedin. S., Hayes, R., Gasparotto, LHS, Borisenko, N., Endres, F.,“AFM and STM studies on the surface interaction of [BMP] TFSA and [EMIm] TFSA ionic liquids with Au \(III\)”, J. Phys. Chem. C, 113:13266–13272, 2009.

Further information

The figure shows digitized data.

The Au(111) electrode was prepared by:
* Annealed at 350°C for 4h under vacuum in a quartz ampule.

Comment left by the curator on the published figure A baseline for zero current was not available and hence was chosen by the curator. The actual data has more noise than the digitized data.

Metadata

Details on the electrochemical system (yaml)

electrodes:
- crystallographicOrientation: poly
  function: counter electrode
  material: Pt
  name: CE
  shape:
    type: wire
- function: reference electrode
  material: Pt
  name: REF
  shape:
    type: wire
- crystallographicOrientation: '111'
  description: Au on mica
  function: working electrode
  geometricElectrolyteContactArea:
    unit: cm-2
    value: 0.3
  material: Au
  name: WE
  preparationProcedure:
    description:
    - "Annealed at 350\xB0C for 4h under vacuum in a quartz ampule."
  source:
    manufacturer: Molecular Imaging
electrolyte:
  components:
  - name: BMP-TFSI
    proportion:
      unit: volume percent
      value: 100
    purity:
      refinement: "vacuum dried at 120 \xB0C"
    source:
      purity:
        grade: ultrapure
      supplier: MERCK/emd
    type: solvent
  temperature:
    unit: K
    value: 298.15
  type: ionic liquid
type: electrochemical

Citation key (bibtex)

@article{atkin_2009_afm_13266,
    author = "Atkin, R and Borisenko, N and Drüschler, M",
    title = "Zein El Abedin",
    journal = "S., Hayes, R., Gasparotto, LHS, Borisenko, N., Endres, F.,“AFM and STM studies on the surface interaction of [BMP] TFSA and [EMIm] TFSA ionic liquids with Au (III)”, J. Phys. Chem. C",
    volume = "113",
    pages = "13266--13272",
    year = "2009"
}

Details about the original figure in the publicaton (yaml).

comment: A baseline for zero current was not available and hence was chosen by the
  curator. The actual data has more noise than the digitized data.
fields:
- name: E
  orientation: horizontal
  reference: Fc/Fc+
  type: number
  unit: V
- name: j
  orientation: vertical
  type: number
  unit: mA / cm2
measurementType: CV
scanRate:
  unit: mV / s
  value: 10.0
simultaneousMeasurements: []
type: digitized

Details about the curation process of this entry (yaml).

process:
- date: '2022-01-10'
  name: Jerome Mayer
  orcid: https://orcid.org/0000-0002-7451-9994
  role: curator
- date: '2024-02-29'
  name: Albert Engstfeld
  orcid: https://orcid.org/0000-0002-9686-3948
  role: reviewer

---