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Au(111) - BMP-TFSI

echemdb identifier: atkin_2009_afm_13266_p4_f4a_solid tags:

A cyclic voltammogramm for Au(111) recorded in BMP-TFSI at a scan rate of 10.0 \(\mathrm{mV\,s^{-1}}\) from Figure 4a in R. Atkin et al. Zein El Abedin. S., Hayes, R., Gasparotto, LHS, Borisenko, N., Endres, F.,“AFM and STM studies on the surface interaction of [BMP] TFSA and [EMIm] TFSA ionic liquids with Au (III)”, J. Phys. Chem. C, 113:13266–13272, 2009.

Further information

The figure shows digitized data.

The Au(111) electrode was prepared by:

Comment left by the curator on the published figure A baseline for zero current was not available and hence was chosen by the curator. The actual data has more noise than the digitized data.

Metadata

Details on the electrochemical system (yaml)
electrodes:
- crystallographic orientation: poly
  function: counter electrode
  material: Pt
  name: CE
  shape:
    type: wire
- function: reference electrode
  material: Pt
  name: REF
  shape:
    type: wire
- crystallographic orientation: '111'
  description: Au on mica
  function: working electrode
  geometric electrolyte contact area:
    unit: cm-2
    value: 0.3
  material: Au
  name: WE
  preparation procedure:
    description:
    - "Annealed at 350\xB0C for 4h under vacuum in a quartz ampule."
  source:
    manufacturer: Molecular Imaging
electrolyte:
  components:
  - name: BMP-TFSI
    proportion:
      unit: volume percent
      value: 100
    purity:
      refinement: "vacuum dried at 120 \xB0C"
    source:
      purity:
        grade: ultrapure
      supplier: MERCK/emd
    type: solvent
  temperature:
    unit: K
    value: 298.15
  type: ionic liquid
type: electrochemical
Citation key (bibtex)
@article{atkin_2009_afm_13266,
    author = "Atkin, R and Borisenko, N and Drüschler, M",
    title = "Zein El Abedin",
    journal = "S., Hayes, R., Gasparotto, LHS, Borisenko, N., Endres, F.,“AFM and STM studies on the surface interaction of [BMP] TFSA and [EMIm] TFSA ionic liquids with Au (III)”, J. Phys. Chem. C",
    volume = "113",
    pages = "13266--13272",
    year = "2009"
}
Details about the original figure in the publicaton (yaml).
comment: A baseline for zero current was not available and hence was chosen by the
  curator. The actual data has more noise than the digitized data.
fields:
- name: E
  orientation: x
  reference: Fc/Fc+
  type: number
  unit: V
- name: j
  orientation: y
  type: number
  unit: mA / cm2
measurement type: CV
scan rate:
  unit: mV / s
  value: 10.0
simultaneous measurements: []
type: digitized
version: 1
Details about the curation process of this entry (yaml).
process:
- date: '2022-01-10'
  name: Jerome Mayer
  orcid: https://orcid.org/0000-0002-7451-9994
  role: curator
- date: '2024-02-29'
  name: Albert Engstfeld
  orcid: https://orcid.org/0000-0002-9686-3948
  role: reviewer