Au(111) - \(\ce{ BMP-FAP }\)

echemdb identifier: atkin_2011_an_6849_f1_black
tags: BCV

A cyclic voltammogramm for Au(111) recorded in \(\ce{ BMP-FAP }\) at a scan rate of \(10 \; \mathrm{mV\,s^{-1}}\) from Figure 1 in R. Atkin et al. An in situ STM/AFM and impedance spectroscopy study of the extremely pure 1-butyl-1-methylpyrrolidinium tris\(pentafluoroethyl\)trifluorophosphate/Au\(111\) interface: potential dependent solvation layers and the herringbone reconstruction. Physical Chemistry Chemical Physics, 13\(15\):6849–6857, 2011.

Further information

The figure shows digitized data.

The Au(111) electrode was prepared by:
* Annealing in a hydrogen flame.

Metadata

Details on the electrochemical system (yaml)

electrodes:
- crystallographicOrientation: poly
  function: counter electrode
  material: Pt
  name: CE
  shape:
    type: wire
- function: reference electrode
  material: Pt
  name: REF
  shape:
    type: wire
- crystallographicOrientation: '111'
  function: working electrode
  material: Au
  name: WE
  preparationProcedure:
    description:
    - Annealing in a hydrogen flame.
electrolyte:
  components:
  - name: BMP-FAP
    proportion:
      unit: volume percent
      value: 100
    purity:
      refinement: "Vacuum dried at 100\xB0C and 1e-3 mbar."
    source:
      supplier: MERCK
    type: solvent
  temperature:
    unit: K
    value: 298.15
  type: ionic liquid
type: electrochemical

Citation key (bibtex)

@article{atkin_2011_an_6849,
    author = {Atkin, Rob and Borisenko, Natalia and Dr{\"u}schler, Marcel and El Abedin, Sherif Zein and Endres, Frank and Hayes, Robert and Huber, Benedikt and Roling, Bernhard},
    title = "An in situ STM/AFM and impedance spectroscopy study of the extremely pure 1-butyl-1-methylpyrrolidinium tris(pentafluoroethyl)trifluorophosphate/Au(111) interface: potential dependent solvation layers and the herringbone reconstruction",
    journal = "Physical Chemistry Chemical Physics",
    volume = "13",
    number = "15",
    pages = "6849--6857",
    year = "2011",
    publisher = "Royal Society of Chemistry"
}

Details about the original figure in the publicaton (yaml).

comment: ''
fields:
- name: E
  orientation: horizontal
  reference: Pt
  type: number
  unit: V
- name: j
  orientation: vertical
  type: number
  unit: uA / cm2
measurementType: CV
scanRate:
  unit: mV / s
  value: 10.0
simultaneousMeasurements: []
type: digitized

Details about the curation process of this entry (yaml).

process:
- date: '2022-06-29'
  name: Maren-Kathrin Heubach
  orcid: https://orcid.org/0000-0002-3769-7169
  role: curator
- date: '2025-08-23'
  name: Albert Engstfeld
  orcid: https://orcid.org/0000-0002-9686-3948
  role: reviewer

---