Au(111) - \(\ce{ MPPip-TFSI }\) + \(0.02 \; \mathrm{M}\) \(\ce{ Li-TFSI }\)

echemdb identifier: berger_2017_lithium_261_f1_pink
tags: BCV

A cyclic voltammogramm for Au(111) recorded in \(\ce{ MPPip-TFSI }\) + \(0.02 \; \mathrm{M}\) \(\ce{ Li-TFSI }\) at a scan rate of \(50 \; \mathrm{mV\,s^{-1}}\) from Figure 1 in C. A. Berger et al. Lithium Deposition from a Piperidinium–based Ionic Liquid: Rapping Dendrites on the Knuckles. ChemElectroChem, 4\(2\):261–265, 2017.

Further information

The figure shows digitized data.

The Au(111) electrode was prepared by:
* Annealed in a hydrogen stream and slowly cooled in Argon.

Metadata

Details on the electrochemical system (yaml)

electrodes:
- crystallographicOrientation: poly
  function: counter electrode
  material: Pt
  name: CE
  shape:
    type: wire
  source:
    manufacturer: MaTecK GmbH
- function: reference electrode
  material: Pt
  name: REF
  source:
    manufacturer: MaTecK GmbH
  type: wire
- crystallographicOrientation: '111'
  function: working electrode
  material: Au
  name: WE
  preparationProcedure:
    description:
    - Annealed in a hydrogen stream and slowly cooled in Argon.
  shape:
    diameter:
      unit: mm
      value: 12
    type: disk
  source:
    manufacturer: MaTecK GmbH
  type: single crystal
electrolyte:
  components:
  - chemicalIdentifiers:
      cas: 608140-12-1
      inchi: InChI=1S/C9H20N.C2F6NO4S2/c1-3-7-10(2)8-5-4-6-9-10;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h3-9H2,1-2H3;/q+1;-1
    name: MPPip-TFSI
    proportion:
      unit: volume percent
      value: 100
    purity:
      refinement: "Vacuum dried at 80\xB0C for 24 h."
    source:
      purity:
        grade: '>99%'
      supplier: IoLiTec
    type: solvent
  - chemicalIdentifiers:
      cas: 90076-65-6
      inchi: InChI=InChI=1S/C2HF6NO4S2.Li/c3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/h9H;
    concentration:
      unit: mol / l
      value: 0.02
    name: Li-TFSI
    type: salt
  temperature:
    unit: K
    value: 298.15
  type: ionic liquid
type: electrochemical

Citation key (bibtex)

@article{berger_2017_lithium_261,
    author = "Berger, Claudia A and Ceblin, Maximilian U and Jacob, Timo",
    title = "Lithium Deposition from a Piperidinium--based Ionic Liquid: Rapping Dendrites on the Knuckles",
    journal = "ChemElectroChem",
    volume = "4",
    number = "2",
    pages = "261--265",
    year = "2017",
    publisher = "Wiley Online Library"
}

Details about the original figure in the publicaton (yaml).

comment: ''
fields:
- name: E
  orientation: horizontal
  reference: Pt
  type: number
  unit: V
- name: j
  orientation: vertical
  type: number
  unit: uA cm-2
measurementType: CV
scanRate:
  unit: mV / s
  value: 50.0
simultaneousMeasurements: []
type: digitized

Details about the curation process of this entry (yaml).

process:
- date: '2022-06-29'
  name: Maren-Kathrin Heubach
  orcid: https://orcid.org/0000-0002-3769-7169
  role: curator
- date: '2024-02-29'
  name: Albert Engstfeld
  orcid: https://orcid.org/0000-0002-9686-3948
  role: reviewer

---