Au(111) - \(\ce{ EMIm-TFSI }\)

echemdb identifier: bonhote_1996_hydrophobic_1168_f7_bold
tags: BCV

A cyclic voltammogramm for Au(111) recorded in \(\ce{ EMIm-TFSI }\) at a scan rate of \(50 \; \mathrm{mV\,s^{-1}}\) from Figure 7 in P. Bonhote et al. Hydrophobic, highly conductive ambient-temperature molten salts. Inorganic chemistry, 35\(5\):1168–1178, 1996.

Further information

The figure shows digitized data.

The Au(111) electrode was prepared by:
* Electrochemical polishing and flame annealing.

Comment left by the curator on the published figure The curve overlaps with other data, only peaks at the vertex potentials are clearly resolved.

Metadata

Details on the electrochemical system (yaml)

atmosphere:
  components:
  - name: Ar
    proportion:
      value: 100
    type: gas
  type: inert chamber
electrodes:
- crystallographicOrientation: poly
  function: counter electrode
  material: Pt
  name: CE
  shape:
    type: disk
- function: reference electrode
  material: Li
  name: REF
  shape:
    type: wire
- crystallographicOrientation: '111'
  function: working electrode
  material: Au
  name: WE
  preparationProcedure:
    description:
    - Electrochemical polishing and flame annealing.
  shape:
    diameter:
      unit: mm
      value: 1
    type: disk
electrolyte:
  components:
  - name: EMIm-TFSI
    proportion:
      unit: volume percent
      value: 100
    source:
      supplier: Homemade
    type: solvent
  temperature:
    unit: K
    value: 298.15
  type: ionic liquid
type: electrochemical

Citation key (bibtex)

@article{bonhote_1996_hydrophobic_1168,
    author = {Bonhote, Pierre and Dias, Ana-Paula and Papageorgiou, Nicholas and Kalyanasundaram, Kuppuswamy and Gr{\"a}tzel, Michael},
    title = "Hydrophobic, highly conductive ambient-temperature molten salts",
    journal = "Inorganic chemistry",
    volume = "35",
    number = "5",
    pages = "1168--1178",
    year = "1996",
    publisher = "ACS Publications"
}

Details about the original figure in the publicaton (yaml).

comment: The curve overlaps with other data, only peaks at the vertex potentials are
  clearly resolved.
fields:
- name: E
  orientation: horizontal
  reference: I-/I3-
  type: number
  unit: V
- name: I
  orientation: vertical
  type: number
  unit: uA
measurementType: CV
scanRate:
  unit: mV / s
  value: 50.0
simultaneousMeasurements: []
type: digitized

Details about the curation process of this entry (yaml).

process:
- date: '2022-06-29'
  name: Maren-Kathrin Heubach
  orcid: https://orcid.org/0000-0002-3769-7169
  role: curator
- date: '2025-08-23'
  name: Albert Engstfeld
  orcid: https://orcid.org/0000-0002-9686-3948
  role: reviewer

---