Au(111) - \(\ce{ BMP-TFSI }\)

echemdb identifier: borisenko_2006_in_6250_f1_c
tags: BCV

A cyclic voltammogramm for Au(111) recorded in \(\ce{ BMP-TFSI }\) at a scan rate of \(10 \; \mathrm{mV\,s^{-1}}\) from Figure 1 in N. Borisenko et al. In situ STM investigation of gold reconstruction and of silicon electrodeposition on Au\(111\) in the room temperature ionic liquid 1-butyl-1-methylpyrrolidinium bis\(trifluoromethylsulfonyl\)imide. The journal of physical chemistry B, 110\(12\):6250–6256, 2006.

Further information

The figure shows digitized data.

The Au(111) electrode was prepared by:
* Annealed at 350 °C for 4h under vacuum.

Comment left by the curator on the published figure Baseline of the y-axis was not given and therby it was selected by the curator. The original data is very noisy.

Metadata

Details on the electrochemical system (yaml)

electrodes:
- crystallographicOrientation: poly
  function: counter electrode
  material: Pt
  name: CE
  shape:
    type: ring
- function: reference electrode
  material: Pt
  name: REF
  shape:
    type: wire
- crystallographicOrientation: '111'
  description: Au on mica
  function: working electrode
  material: Au
  name: WE
  preparationProcedure:
    description:
    - "Annealed at 350 \xB0C for 4h under vacuum."
  source:
    manufacturer: Molecular Imaging
electrolyte:
  components:
  - comment: < 10 ppm chloride, Li-free synthesis.
    name: BMP-TFSI
    proportion:
      unit: volume percent
      value: 100
    source:
      purity:
        grade: ultrapure
      supplier: Merck/EMD
    type: solvent
  temperature:
    unit: K
    value: 298.15
  type: ionic liquid
type: electrochemical

Citation key (bibtex)

@article{borisenko_2006_in_6250,
    author = "Borisenko, N and Zein El Abedin, Sh and Endres, F",
    title = "In situ STM investigation of gold reconstruction and of silicon electrodeposition on Au(111) in the room temperature ionic liquid 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide",
    journal = "The journal of physical chemistry B",
    volume = "110",
    number = "12",
    pages = "6250--6256",
    year = "2006",
    publisher = "ACS Publications"
}

Details about the original figure in the publicaton (yaml).

comment: Baseline of the y-axis was not given and therby it was selected by the curator.
  The original data is very noisy.
fields:
- name: E
  orientation: horizontal
  reference: Fc/Fc+
  type: number
  unit: V
- name: I
  orientation: vertical
  type: number
  unit: uA
measurementType: CV
scanRate:
  unit: mV / s
  value: 10.0
simultaneousMeasurements: []
type: digitized

Details about the curation process of this entry (yaml).

process:
- date: '2022-01-10'
  name: Jerome Mayer
  orcid: https://orcid.org/0000-0002-7451-9994
  role: curator
- date: '2025-08-23'
  name: Albert Engstfeld
  orcid: https://orcid.org/0000-0002-9686-3948
  role: reviewer

---