Pt(110) - \(0.001 \; \mathrm{M}\) \(\ce{ HClO4 }\) + \(1 \; \mathrm{M}\) \(\ce{ NaClO4 }\) + \(0.0001 \; \mathrm{M}\) \(\ce{ Cu }\)

echemdb identifier: durand_1992_insitu_1977_f1a_solid
tags: BCV , Cu UPD

A cyclic voltammogramm for Pt(110) recorded in \(0.001 \; \mathrm{M}\) \(\ce{ HClO4 }\) + \(1 \; \mathrm{M}\) \(\ce{ NaClO4 }\) + \(0.0001 \; \mathrm{M}\) \(\ce{ Cu }\) at a scan rate of \(10 \; \mathrm{mV\,s^{-1}}\) from Figure 1a in R. Durand et al. In situ X-ray absorption spectroscopy study of underpotential deposition of copper on platinum \(100\). Electrochimica acta, 37\(11\):1977–1982, 1992.

Further information

The figure shows digitized data.

The Pt(110) electrode was prepared by:
* Annealed in an H2-O2 flame.

Comment left by the curator on the published figure The original data is rather noisy due to low resolution of the document.

Metadata

Details on the electrochemical system (yaml)

electrodes:
- function: reference electrode
  name: REF
  type: RHE
- crystallographicOrientation: '110'
  function: working electrode
  geometricElectrolyteContactArea:
    unit: cm-2
  material: Pt
  name: WE
  preparationProcedure:
    description:
    - Annealed in an H2-O2 flame.
electrolyte:
  components:
  - name: water
    proportion:
      unit: volume percent
      value: 100
    type: solvent
  - concentration:
      unit: mol / l
      value: 0.001
    name: HClO4
    type: acid
  - concentration:
      unit: mol / l
      value: 1
    name: NaClO4
    type: salt
  - comment: Cu-ion source not provied.
    concentration:
      unit: mol / l
      value: 0.0001
    name: Cu
    purity:
      grade: 5N
    type: salt
  - name: Ar
    pressure:
      unit: 1
      value: bar
    proportion:
      value: 100
    type: gas
  ph:
    uncertainty:
      value: 0.1
    value: 0.29
  temperature:
    unit: K
    value: 298.15
  type: aqueous
type: electrochemical

Citation key (bibtex)

@article{durand_1992_insitu_1977,
    author = "Durand, R and Faure, R and Aberdam, D and Salem, C and Tourillon, G and Guay, D and Ladouceur, M",
    title = "In situ X-ray absorption spectroscopy study of underpotential deposition of copper on platinum (100)",
    journal = "Electrochimica acta",
    volume = "37",
    number = "11",
    pages = "1977--1982",
    year = "1992",
    publisher = "Elsevier"
}

Details about the original figure in the publicaton (yaml).

comment: The original data is rather noisy due to low resolution of the document.
fields:
- name: E
  orientation: horizontal
  reference: SCE
  type: number
  unit: V
- name: I
  orientation: vertical
  type: number
  unit: uA
measurementType: CV
scanRate:
  unit: mV / s
  value: 10.0
simultaneousMeasurements: []
type: digitized

Details about the curation process of this entry (yaml).

process:
- date: '2022-02-18'
  name: Tobias Schmider
  orcid: https://orcid.org/0000-0002-2911-2925
  role: curator

---