Au(111) - \(\ce{ EMIm-TFSI }\)

echemdb identifier: endres_2006_probing_1377_f11_a
tags: BCV

A cyclic voltammogramm for Au(111) recorded in \(\ce{ EMIm-TFSI }\) at a scan rate of \(10 \; \mathrm{mV\,s^{-1}}\) from Figure 11 in F. Endres et al. Probing lithium and alumina impurities in air-and water stable ionic liquids by cyclic voltammetry and in situ scanning tunneling microscopy. Zeitschrift für Physikalische Chemie, 220\(10\):1377–1394, 2006.

Further information

The figure shows digitized data.

Preparation procedure not available.

Comment left by the curator on the published figure I-axis offset not given. Basline estimate by curator.

Metadata

Details on the electrochemical system (yaml)

electrodes:
- crystallographicOrientation: poly
  function: counter electrode
  material: Pt
  name: CE
  shape:
    type: ring
- function: reference electrode
  material: Pt
  name: REF
  shape:
    type: wire
- crystallographicOrientation: '111'
  description: Au on mica
  function: working electrode
  geometricElectrolyteContactArea:
    unit: cm-2
    value: 0.3
  material: Au
  name: WE
  source:
    manufacturer: Molecular Imaging
  type: single crystal
electrolyte:
  components:
  - chemicalIdentifiers:
      cas: 174899-82-2
      inchi: InChI=1S/C6H11N2.C2F6NO4S2/c1-3-8-5-4-7(2)6-8;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h4-6H,3H2,1-2H3;/q+1;-1
    name: EMIm-TFSI
    proportion:
      unit: volume percent
      value: 100
    purity:
      refinement: "Metathesis with Li, Cl and washed with alumina and washed with\
        \ water and dried under vacuum at 100\xB0C for 10 h."
    type: solvent
  temperature:
    unit: K
    value: 298.15
  type: ionic liquid
type: electrochemical

Citation key (bibtex)

@article{endres_2006_probing_1377,
    author = "Endres, Frank and El Abedin, Sherif Zein and Borissenko, Natalia",
    title = "Probing lithium and alumina impurities in air-and water stable ionic liquids by cyclic voltammetry and in situ scanning tunneling microscopy",
    journal = "Zeitschrift für Physikalische Chemie",
    volume = "220",
    number = "10",
    pages = "1377--1394",
    year = "2006",
    publisher = "De Gruyter Oldenbourg"
}

Details about the original figure in the publicaton (yaml).

comment: I-axis offset not given. Basline estimate by curator.
fields:
- name: E
  orientation: horizontal
  reference: Fc/Fc+
  type: number
  unit: V
- name: I
  orientation: vertical
  type: number
  unit: mA
measurementType: CV
scanRate:
  unit: mV / s
  value: 10.0
simultaneousMeasurements: []
type: digitized

Details about the curation process of this entry (yaml).

process:
- date: '2023-02-17'
  name: Maren-Kathrin Heubach
  orcid: https://orcid.org/0000-0002-3769-7169
  role: curator
- date: '2025-08-23'
  name: Albert Engstfeld
  orcid: https://orcid.org/0000-0002-9686-3948
  role: reviewer

---