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Ag(100) - 0.03 M KClO4 + 0.02 M KCl

echemdb identifier: hamad_2003_electrosorption_211_f1a_solid tags: BCV

A cyclic voltammogramm for Ag(100) recorded in 0.03 M KClO4 + 0.02 M KCl at a scan rate of 50.0 \(\mathrm{mV\,s^{-1}}\) from Figure 1a in I. Abou Hamad et al. Electrosorption of Br and Cl on Ag(100): experiments and computer simulations. Journal of Electroanalytical Chemistry, 554:211–219, 2003.

Further information

The figure shows digitized data.

The Ag(100) electrode was prepared by:

Comment left by the curator on the published figure Combined with Monte-Carlo simulation.

Metadata

Details on the electrochemical system (yaml)
electrodes:
- function: counter electrode
  material: Pt
  name: CE
  shape:
    type: wire
- function: reference electrode
  name: REF
  source:
    manufacturer: SI Analytics
  type: SCE
- crystallographic orientation: '100'
  function: working electrode
  material: Ag
  name: WE
  preparation procedure:
    description:
    - Electrode etched with a cyanide solution.
    - Rinsed with Milli-Q water.
    - Annealed in an H2 flame for 30 s.
electrolyte:
  components:
  - concentration:
      unit: mol / l
      value: 0.03
    name: KClO4
    type: salt
  - name: water
    type: solvent
  - concentration:
      unit: mol / l
      value: 0.02
    name: KCl
    type: salt
  temperature:
    unit: K
    value: 293
  type: aqueous
type: electrochemical
Citation key (bibtex)
@article{hamad_2003_electrosorption_211,
    author = "Abou Hamad, I and Wandlowski, Th and Brown, G and Rikvold, PA",
    title = "Electrosorption of Br and Cl on Ag(100): experiments and computer simulations",
    journal = "Journal of Electroanalytical Chemistry",
    volume = "554",
    pages = "211--219",
    year = "2003",
    publisher = "Elsevier"
}
Details about the original figure in the publicaton (yaml).
comment: Combined with Monte-Carlo simulation.
fields:
- name: E
  orientation: x
  reference: SCE
  type: number
  unit: V
- name: j
  orientation: y
  type: number
  unit: uA / cm2
measurement type: CV
scan rate:
  unit: mV / s
  value: 50.0
simultaneous measurements:
- capacitance
- chronocoulometry
type: digitized
version: 1
Details about the curation process of this entry (yaml).
process:
- date: '2021-10-18'
  name: Markus Schilling
  orcid: https://orcid.org/0000-0003-2684-3711
  role: curator
- date: '2022-01-21'
  name: Albert Engstfeld
  orcid: https://orcid.org/0000-0002-9686-3948
  role: reviewer