Cu(111) - \(0.1 \; \mathrm{M}\) \(\ce{ NaOH }\)

echemdb identifier: jovic_2002_surface_531_f1a_black
tags: BCV

A cyclic voltammogramm for Cu(111) recorded in \(0.1 \; \mathrm{M}\) \(\ce{ NaOH }\) at a scan rate of \(100 \; \mathrm{mV\,s^{-1}}\) from Figure 1a in V. Jović et al. Surface reconstruction during the adsorption/desorption of OH species onto Cu\(111\) and Cu\(100\) in 0.1 M NaOH solution. Journal of the Serbian Chemical Society, 67\(7\):531–546, 2002

Further information

The figure shows digitized data.

The Cu(111) electrode was prepared by:

• Mechanically polished on fine grade emery papers.
• Electrochemically polished in a phosphoric acid solution at constant voltage.
• Thoroughly washed with pure water, cleaned in H2SO4 and washed again with pure water. Preparation reference: http://dx.doi.org/10.2298/JSC0207531J

Metadata

Details on the electrochemical system (yaml)

electrodes:
- function: counter electrode
  material: Pt
  name: CE
  type: sheet
- function: reference electrode
  name: RE
  type: Hg/HgO-0.1M-NaOH
- crystallographicOrientation: '111'
  function: working electrode
  geometricElectrolyteContactArea:
    unit: cm2
    value: 5.05
  material: Cu
  name: WE
  preparationProcedure:
    description:
    - Mechanically polished on fine grade emery papers.
    - Electrochemically polished in a phosphoric acid solution at constant voltage.
    - Thoroughly washed with pure water, cleaned in H2SO4 and washed again with pure
      water.
    url: http://dx.doi.org/10.2298/JSC0207531J
  shape:
    diameter:
      unit: cm
      value: 2.54
  source:
    supplier: Monocrystals Company
  type: single crystal
electrolyte:
  components:
  - name: water
    source:
      quality: EASY pure UV
      supplier: Barnstead
    type: solvent
  - concentration:
      unit: mol / l
      value: 0.1
    name: NaOH
    source:
      purity:
        grade: supra pure
      supplier: Fischer
    type: base
  - name: N2
    purity:
      unit: pct
      value: 99.999
    type: gas
  type: aqueous
type: electrochemical

Citation key (bibtex)

@article{jovic_2002_surface_531,
    author = "Jović, Vladimir and Jović, Borka",
    title = "Surface reconstruction during the adsorption/desorption of OH species onto Cu(111) and Cu(100) in 0.1 M NaOH solution",
    journal = "Journal of the Serbian Chemical Society",
    volume = "67",
    number = "7",
    pages = "531--546",
    year = "2002",
    publisher = "Belgrade: Serbian Chemical Society"
}

Details about the original figure in the publicaton (yaml).

comment: ''
fields:
- name: E
  orientation: horizontal
  reference: SHE
  type: number
  unit: V
- name: j
  orientation: vertical
  type: number
  unit: uA / cm2
measurementType: CV
scanRate:
  unit: mV / s
  value: 100.0
simultaneousMeasurements: []
type: digitized

Details about the curation process of this entry (yaml).

process:
- date: '2026-04-04'
  name: Valerie Link
  orcid: https://orcid.org/0009-0004-3341-1452
  role: curator

---