Pt(111) - \(0.001 \; \mathrm{M}\) \(\ce{ HClO4 }\) + \(0.1 \; \mathrm{M}\) \(\ce{ KClO4 }\)

echemdb identifier: li_2000_chronocoulometric_95_f1_solid
tags: BCV

A cyclic voltammogramm for Pt(111) recorded in \(0.001 \; \mathrm{M}\) \(\ce{ HClO4 }\) + \(0.1 \; \mathrm{M}\) \(\ce{ KClO4 }\) at a scan rate of \(20 \; \mathrm{mV\,s^{-1}}\) from Figure 1 in N. Li et al. Chronocoulometric studies of chloride adsorption at the Pt\(111\) electrode surface. Journal of Electroanalytical Chemistry, 491\(1\-2\):95–102, 2000.

Further information

The figure shows digitized data.

The Pt(111) electrode was prepared by:
* A Pt single crystal bead was cut along the (111) orientation.
* The electrode was annealed in a hydrogen+air flame.
* Cooled in a hydrogen atmosphere.
* Quenched with ultrapure water.

Comment left by the curator on the published figure The scan rate is not given in the publication. It was manually determined from the charge integration as 20 mV / s.

Metadata

Details on the electrochemical system (yaml)

electrodes:
- function: counter electrode
  material: Pt
  name: CE
  shape:
    type: coil
- function: reference electrode
  name: REF
  type: SCE
- crystallographicOrientation: '111'
  function: working electrode
  geometricElectrolyteContactArea:
    unit: cm2
    value: 0.043
  material: Pt
  name: WE
  preparationProcedure:
    description:
    - A Pt single crystal bead was cut along the (111) orientation.
    - The electrode was annealed in a hydrogen+air flame.
    - Cooled in a hydrogen atmosphere.
    - Quenched with ultrapure water.
electrolyte:
  components:
  - concentration:
      unit: mmol / l
      value: 1
    name: HClO4
    type: acid
  - name: water
    type: solvent
  - concentration:
      unit: mol / l
      value: 0.1
    name: KClO4
    type: salt
  ph:
    value: 3
  temperature:
    unit: K
    value: 298.15
  type: aqueous
type: electrochemical

Citation key (bibtex)

@article{li_2000_chronocoulometric_95,
    author = "Li, Nanhai and Lipkowski, Jacek",
    title = "Chronocoulometric studies of chloride adsorption at the Pt(111) electrode surface",
    journal = "Journal of Electroanalytical Chemistry",
    volume = "491",
    number = "1-2",
    pages = "95--102",
    year = "2000",
    publisher = "Elsevier"
}

Details about the original figure in the publicaton (yaml).

comment: The scan rate is not given in the publication. It was manually determined
  from the charge integration as 20 mV / s.
fields:
- name: E
  orientation: horizontal
  reference: SCE
  type: number
  unit: mV
- name: j
  orientation: vertical
  type: number
  unit: uA / cm2
measurementType: CV
scanRate:
  unit: mV / s
  value: 20.0
simultaneousMeasurements: []
type: digitized

Details about the curation process of this entry (yaml).

process:
- date: '2021-11-17'
  name: Markus Schilling
  orcid: https://orcid.org/0000-0003-2684-3711
  role: curator
- date: '2022-01-21'
  name: Albert Engstfeld
  orcid: https://orcid.org/0000-0002-9686-3948
  role: reviewer

---