Ir(100) - \(0.1 \; \mathrm{M}\) \(\ce{ KClO4 }\)

echemdb identifier: pajkossy_2007_voltammetry_113_f3b_solid
tags: BCV

A cyclic voltammogramm for Ir(100) recorded in \(0.1 \; \mathrm{M}\) \(\ce{ KClO4 }\) at a scan rate of \(10 \; \mathrm{mV\,s^{-1}}\) from Figure 3b in T. Pajkossy et al. Voltammetry and impedance measurements of Ir\(100\) electrodes in aqueous solutions. Journal of Electroanalytical chemistry, 600\(1\):113–118, 2007.

Further information

The figure shows digitized data.

The Ir(100) electrode was prepared by:

• High temperature annealing at about 1900°C in a nitrogen-hydrogen atmosphere for 1 min.
• Cool down in the gas stream for 2 min.
• Transferred to the electrochemical cell under protecting gas stream.
• Hanging meniscus configuration.

Metadata

Details on the electrochemical system (yaml)

electrodes:
- crystallographicOrientation: '100'
  function: working electrode
  material: Ir
  name: WE
  preparationProcedure:
    description:
    - "High temperature annealing at about 1900\xB0C in a nitrogen-hydrogen atmosphere\
      \ for 1 min."
    - Cool down in the gas stream for 2 min.
    - Transferred to the electrochemical cell under protecting gas stream.
    - Hanging meniscus configuration.
  shape:
    diameter:
      unit: mm
      value: 4.0
  source:
    supplier: MaTecK GmbH
  type: single crystal
electrolyte:
  comment: details see https://doi.org/10.1016/0022-0728(96)04700-6
  components:
  - name: water
    source:
      refinement: Milli-Q
    type: solvent
  - concentration:
      unit: mol / l
      value: 0.1
    name: KClO4
    purity:
      grade: suprapur
    type: salt
  - name: N2
    purity:
      grade: 5N
    type: gas
  ph:
    value: 10
  temperature:
    uncertainty:
      unit: degC
      value: 1.0
    unit: degC
    value: 20
  type: aqueous
type: electrochemical

Citation key (bibtex)

@article{pajkossy_2007_voltammetry_113,
    author = "Pajkossy, Tamas and Kibler, Ludwig A and Kolb, Dieter M",
    title = "Voltammetry and impedance measurements of Ir(100) electrodes in aqueous solutions",
    journal = "Journal of Electroanalytical chemistry",
    volume = "600",
    number = "1",
    pages = "113--118",
    year = "2007",
    publisher = "Elsevier"
}

Details about the original figure in the publicaton (yaml).

comment: ''
fields:
- name: E
  orientation: horizontal
  reference: RHE
  type: number
  unit: V
- name: j
  orientation: vertical
  type: number
  unit: uA / cm2
measurementType: CV
scanRate:
  unit: mV / s
  value: 10.0
simultaneousMeasurements: []
type: digitized

Details about the curation process of this entry (yaml).

process:
- date: '2026-02-04'
  name: Valerie Link
  orcid: https://orcid.org/0009-0004-3341-1452
  role: curator

---